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Sodium tert-Butoxide (STB) in Tetrahydrofuran

Sodium tert-Butoxide (STB) in Tetrahydrofuran

Specifications of Sodium tert-Butoxide (STB) in Tetrahydrofuran

  • Assay: 19% to 21%
  • Free Alkalinity (NaOH Na2CO3) as NaOH (%W/W): Max. 1%

Physical & Chemical Properties

CAS Number 865-48-5
Molecular Formula C4H9NaO
Molecular Weight 96.10 g/mol
Appearance Slightly yellow to brown colour viscous liquid
Melting Point 180°C
Flash Point 250°C

Applications of Sodium tert-Butoxide (STB) in Tetrahydrofuran

  • Sterically hindered base for eliminations and base-promoted cross-couplings (Buchwald, etc.).

  • Liquid formulation reduces weighing errors and improves safety/scale reproducibility.
  • Standardized molarity simplifies stoichiometry control in production.

Advantages of Standardized molarity simplifies stoichiometry control in production.

  • Strong, sterically hindered base with high solubility in THF – reliable for many base-promoted transformations.

  • Liquid formulation reduces weighing errors and dust exposure – better process control at scale.
  • Effective in cross-coupling and Buchwald/Hartwig-type conditions where tert-butoxide base is preferred.
  • Commercial solutions available in defined molarity for reproducible reaction stoichiometry.

Packing:

  • SS Drum

Shipping Regulation:

H.S. Code 29051990
UN Number UN 3206
packaging Group Class III

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